On cold nights, a greenhouse loses heat fast through the skin of the structure. A single sheet of poly has minimal insulating value, so the warm interior air "pushes" heat outward.
With double layer, the inflation system traps a layer of still air between the films. Still air is a poor conductor of heat, so the rate of heat transfer drops. In real-world terms, your heater cycles less often to maintain the same setpoint.
Important: the upgrade only performs well if the structure is reasonably tight. Big leaks at end walls, doors, or ground-to-film edges can dominate heat loss and reduce the value of the second layer.